Molecular oxidation-reduction junctions for artificial photosynthetic overall reaction.

ABSTRACT: Constructing redox semiconductor heterojunction photocatalysts is the most effective and important means to complete the artificial photosynthetic overall reaction (i.e., coupling CO₂ photoreduction and water photo-oxidation reactions). However, multiphase hybridization essence and inhomogeneous junction distribution in these catalysts extremely limit the diverse design and regulation of the modes of photogenerated charge separation and transfer pathways, which are crucial factors to improve photocatalytic performance. Here, we develop molecular oxidation-reduction (OR) junctions assembled with oxidative cluster (PMo₁₂, for water oxidation) and reductive cluster (Ni₅, for CO₂ reduction) in a direct (d-OR), alternant (a-OR), or symme

SUBMITTER: Zhang L 

PROVIDER: S-EPMC9546620 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature