Charge-Separated Reactive Intermediates from the UV Photodissociation of Chlorobenzene in Solution.

ABSTRACT: Although ultraviolet (UV)-induced photochemical cleavage of carbon-halogen bonds in gaseous halocarbons is mostly homolytic, the photolysis of chlorobenzene in solution has been proposed to produce a phenyl cation, c-C₆H₅⁺, which is a highly reactive intermediate of potential use in chemical synthesis and N₂ activation. Any evidence for such a route to phenyl cations is indirect, with uncertainty remaining about the possible mechanism. Here, ultrafast transient absorption spectroscopy of UV-excited (λ = 240 and 270 nm) chlorobenzene solutions in fluorinated (perfluorohexane) and protic (ethanol and 2,2,2-trifluoroethanol) solvents reveals a broad electronic absorption band centered at 540 nm that is assigned to an isomer of chlorobenzene with bot

SUBMITTER: Kao MH 

PROVIDER: S-EPMC9549464 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature