Kinetic and Products Study of the Atmospheric Degradation of trans-2-Hexenal with Cl Atoms.

ABSTRACT: The gas-phase reaction between trans-2-hexenal (T2H) and chlorine atoms (Cl) was studied using three complementary experimental setups at atmospheric pressure and room temperature. In this work, we studied the rate constant for the titled oxidation reaction as well as the formation of the gas-phase products and secondary organic aerosols (SOAs). The rate constant of the T2H + Cl reaction was determined using the relative method in a simulation chamber using proton-transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) to monitor the loss of T2H and the reference compound. An average reaction rate constant of (3.17 ± 0.72) × 10^-10 cm³ molecule^-1 s^-1 was obtained. From this, the atmospheric lifetime of T2H due to Cl reaction was est

SUBMITTER: Grira A 

PROVIDER: S-EPMC9549468 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature