A mechanistic study of the dopant-induced breakdown in halide perovskites using solid state energy storage devices.

ABSTRACT: Doping halide perovskites (HPs) with extrinsic species, such as alkali metal ions, plays a critical, albeit often elusive role in optimising optoelectronic devices. Here, we use solid state lithium ion battery inspired devices with a polyethylene oxide-based polymer electrolyte to dope HPs controllably with lithium ions. We perform a suite of operando material analysis techniques while dynamically varying Li doping concentrations. We determine and quantify three doping regimes; a safe regime, with doping concentrations of <10²⁰ cm^-3 (2% Li : Pb mol%) in which the HP may be modified without detrimental effect to its structure; a minor decomposition regime, in which the HP is partially transformed but remains the dominant species; and a major decomposition regime

SUBMITTER: Mathieson AGM 

PROVIDER: S-EPMC9555316 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature