Stereomutation and chiroptical bias in the kinetically controlled supramolecular polymerization of cyano-luminogens.

ABSTRACT: The synthesis of two pairs of enantiomeric cyano-luminogens 1 and 2, in which the central chromophore is a p-phenylene or a 2,5-dithienylbenzene moiety, respectively, is described and their supramolecular polymerization under kinetic and thermodynamic control investigated. Compounds 1 and 2 form supramolecular polymers by quadruple H-bonding arrays between the amide groups and the π-stacking of the central aromatic moieties. In addition, the peripheral benzamide units are able to form intramolecularly H-bonded pseudocycles that behave as metastable monomer M* thus affording kinetically and thermodynamically controlled aggregated species AggI and AggII. The chiroptical and emissive features of compounds 1 and 2 strongly depend on the aggregation state and the nature of the central ar

SUBMITTER: Lopez-Gandul L 

PROVIDER: S-EPMC9555562 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature