Structural diversity in three-dimensional self-assembly of nanoplatelets by spherical confinement.

ABSTRACT: Nanoplatelets offer many possibilities to construct advanced materials due to new properties associated with their (semi)two-dimensional shapes. However, precise control of both positional and orientational order of the nanoplatelets in three dimensions, which is required to achieve emerging and collective properties, is challenging to realize. Here, we combine experiments, advanced electron tomography and computer simulations to explore the structure of supraparticles self-assembled from nanoplatelets in slowly drying emulsion droplets. We demonstrate that the rich phase behaviour of nanoplatelets, and its sensitivity to subtle changes in shape and interaction potential can be used to guide the self-assembly into a wide range of different structures, offering precise control over both ori

SUBMITTER: Wang D 

PROVIDER: S-EPMC9556815 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature