Dimerization of sub-nanoscale molecular clusters affords broadly tuneable viscoelasticity above the glass transition temperature.

ABSTRACT: Materials with promising mechanical performance generally demonstrate requirements for the critical sizes of their key building units, e.g. entanglements and crystal grains. Herein, only with van der Waals interaction, viscoelasticity with broad tunability has been facilely achieved below the critical size limits: the dimers of ∼1 nm polyhedral oligomeric silsesquioxane (POSS) with M _w < 4 kD and size < 5 nm, which demonstrate distinct material physics compared to that of polymer nanocomposites of POSS. The dimeric POSSs are confirmed by scattering and calorimetrical measurements to be intrinsic glassy materials with glass transition temperatures (T _gs) lower than room temperature. From rheological studies, their viscoelasticity can be broadly tun

SUBMITTER: Zhou X 

PROVIDER: S-EPMC9557216 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature