Selective Ligand-Doped Liquid Crystal-Based Sensing Platform for Detection of ClO^- Ions in Aqueous Media.

ABSTRACT: The liquid crystal (LC) detection platform has been fabricated for the detection of hypochlorite ions (ClO^-) in aquatic solutions. In this system, an imine consisting of the ligand (E)-2-((4-(diethylamino)-2-hydroxybenzylidene)amino)-5-methoxybenzenesulfonic acid (MBA) was doped in 4-cyano-4'-pentyl biphenyl as a selecting LC for ClO^-. When immersing the platform in a solution containing ClO^-, hypochlorite appears to react with the imine bond in the MBA, and cause it to cleave, which eventually disrupts the direction of LC and causes a dark-to-bright conversion of the LC image. The detection limit for ClO^- is 0.05 μM. This sensory platform was unresponsive to NO₃ ^-, BrO₃ ^-, CH₃COO

SUBMITTER: Moeinpour F 

PROVIDER: S-EPMC9558706 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature