Growth modes of single-walled carbon nanotubes on catalysts.

ABSTRACT: Understanding the growth mechanism of single-walled carbon nanotubes (SWCNTs) and achieving selective growth requires insights into the catalyst structure-function relationship. Using an in situ aberration-corrected environmental transmission electron microscope, we reveal the effects of the state and structure of catalysts on the growth modes of SWCNTs. SWCNTs grown from molten catalysts via a vapor-liquid-solid process generally present similar diameters to those of the catalysts, indicating a size correlation between nanotubes and catalysts. However, SWCNTs grown from solid catalysts via a vapor-solid-solid process always have smaller diameters than the catalysts, namely, an independent relationship between their sizes. The diameter distribution of SWCNTs grown from crystalline Co₇

SUBMITTER: Yang F 

PROVIDER: S-EPMC9565797 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature