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Towards Sustainable Carbon Return from Waste to Industry via C₂-Type Molecular Unit.

ABSTRACT: A general possibility of a sustainable cycle for carbon return to high-value-added products is discussed by turning wastes into acetylene. Pyrolyzed solid municipal wastes, pyrolyzed used cationic exchangers, and other waste carbon sources were studied in view of the design of a sustainable cycle for producing calcium carbide and acetylene. The yields of calcium carbide from carbon wastes were as high as those from industrial fossil raw materials (coke, charcoal, etc.). Conversion of carbon-containing wastes to calcium carbide provides an excellent opportunity to make acetylene, which is directly compatible with modern industry. Overall, the process returns carbon-containing wastes back to sustainable cycles to produce high-value-added products involving only C₂-type molecules (calcium carbide and acetylene). Calcium carbide may be stored and transported, and on-demand acetylene generation is easy to realize. Upon incorporation into the waste processing route, calcium carbide may be an efficient carbon reservoir for quick industrial uptake.

SUBMITTER: Rodygin KS

PROVIDER: S-EPMC9569557 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature

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Towards Sustainable Carbon Return from Waste to Industry via C<sub>2</sub>-Type Molecular Unit.

Rodygin Konstantin S KS Lotsman Kristina A KA Samoylenko Dmitriy E DE Kuznetsov Viktor M VM Ananikov Valentine P VP

International journal of molecular sciences 20221005 19

A general possibility of a sustainable cycle for carbon return to high-value-added products is discussed by turning wastes into acetylene. Pyrolyzed solid municipal wastes, pyrolyzed used cationic exchangers, and other waste carbon sources were studied in view of the design of a sustainable cycle for producing calcium carbide and acetylene. The yields of calcium carbide from carbon wastes were as high as those from industrial fossil raw materials (coke, charcoal, etc.). Conversion of carbon-cont ...[more]

PMID: 36233131

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Project description:BackgroundThe health care sector is among the most carbon-intensive sectors, contributing to societal problems like climate change. Previous research demonstrated that especially the use of personal protective equipment (e.g., aprons) in critical care contributes to this problem. To reduce personal protective equipment waste, new sustainable policies are needed. Policies are only effective if people comply.AimOur aim is to examine whether compliance with sustainable policies in critical care can be increased through behavioural influencing. Specifically, we examined the effectiveness of two sets of nudges (i.e., a Prime + Visual prompt nudge and a Social norm nudge) on decreasing apron usage in an intensive care unit (ICU).Study designWe conducted a field experiment with a pre- and post-intervention measurement. Upon the introduction of the new sustainable policy, apron usage data were collected for 9 days before (132 observations) and 9 days after (114 observations) the nudge interventions were implemented.ResultsNeither the Prime + Visual prompt nudge, nor the Social norm nudge decreased apron usage.ConclusionsWhile previous studies have found that primes, visual nudges and social norm nudges can increase sustainable behaviour, we did not find evidence for this in our ICU field experiment. Future research is needed to determine whether this null finding reflects reality, or whether it was due to methodological decisions and limitations of the presented experiment.Relevance to clinical practiceThe presented study highlights the importance of studying behavioural interventions that were previously proven successful in the lab and in other field contexts, in the complex setting of critical care. Results previously found in other contexts may not generalize directly to a critical care context. The unique characteristics of the critical care context also pose methodological challenges that may have affected the outcomes of this experiment.

Project description:Solid waste generation is attested to be unavoidable product of human activities. Sustainable management of such waste is a pressing challenge faced in many developing countries today. The study was motivated by the fast growing population and the inefficient waste management system threatening the public health and the image of Shashemene city in Ethiopia. The objectives of the study were: to explore the existing household solid waste management practices, to examine the current governance system of municipal solid waste management, to investigate the contemporary challenges and opportunities of municipal solid waste management, and forward integrated and sustainable municipal solid waste management system for Shashemene city. Data were collected from sampled households, key informants, focus groups, and the city's environment. Data were analyzed by employing quantitative and qualitative methods. 94.8 % of the respondents opined that the solid waste generated in their city is organic in nature (Ash, and sweeps; leftover food, and vegetable peels; paper, and cardboards; green leaves, and grass; and cattle dung). 96.7 % of respondent households opined that they have temporary waste storage in their yards and trash bags were asserted to be widely used (87.6 %) in handling the trash in the courtyard. The waste sorting and recovering practices among the residents is very low and is certainly the major cause for inefficient and unsustainable management system of municipal solid waste in Shashemene city. Generally, a grand mean of 2.23 confirmed the absence of good governance in municipal solid waste management system in Shashemene city. Moreover, the significant proportion of responses ( ≥ 50 %) for each of the nine principles of good governance as either poor or very poor asserted governance failure of the municipal solid waste management system in Shashemene city. The results of the study confirmed that low public awareness on waste management; inadequate collection capacity; poor integration and coordination of stakeholders; environmentally unsound dump site; and illegal dumping by key stakeholders are the major challenges underpinning the unsustainable municipal solid waste management in the city. It is recommended that Shashemene city must adopt integrated sustainable municipal solid waste management system to substantially enhance the waste management service in the city leading to ultimate advancement of public health and environmental quality.

Project description:Waste from the sugar cane industry and alcohol distilleries is one of the sources of water pollution, and the degradation of this effluent is a very challenging task. Photocatalytic degradation can be an attractive alternative to conventional degradation processes. A vanadium-doped TiO2 (V-TiO2) photocatalyst for the degradation of spent wash and industrial dyes has been studied and reported here. V-doped TiO2 nanoparticles were prepared using a sol-gel method based on aqueous titanium peroxide with titanium isopropoxide as the Ti precursor and V2O5 as the V precursor. In order to observe the effect of the dopant on sol-gel behaviour, physicochemical and structural properties, the concentration of V was varied between 1.0% and 5% by weight. The crystallization temperature and time were optimized to obtain the required phase of V-TiO2. The physicochemical and structural characteristics of the V-doped TiO2 catalyst were determined using Brunauer-Emmett-Teller (BET), X-ray diffraction, FESEM, TEM, TG, FT-IR, Raman, PL and UV-visible spectroscopic techniques. UV-visible analysis showed a red shift in the absorption edge of TiO2 upon doping with V metal, which suggested an increase in the absorption of visible light due to a decrease in the effective band gap. The application potential of the V-TiO2 catalyst was studied via the degradation of sugar industry waste (spent wash) and Jakofix red dye (HE 8BN) under natural sunlight, as well as a standard artificial solar energy source (Xe lamp). The highest activity was observed for a 1% V-TiO2 photocatalyst for the degradation of spent wash and Jakofix red dye under natural sunlight. The degradation of coloured compounds in spent wash was monitored by gel permeation chromatography (GPC), which showed the degradation of high-molecular-weight compounds into low-molecular-weight fractions. The catalyst decomposed 90% of Jakofix red dye (HE 8BN) in 3.5 h and 65% of spent wash in 5 h under irradiation with natural sunlight, whereas Degussa P-25 TiO2 was only able to decompose 35% of the dye and 20% of spent wash under identical reaction conditions. A cycling stability test showed the high stability and reusability of the photocatalyst for degradation reactions, with a recovery of around 94-96%.

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Towards Sustainable Carbon Return from Waste to Industry via C₂-Type Molecular Unit.

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Towards Sustainable Carbon Return from Waste to Industry via C<sub>2</sub>-Type Molecular Unit.

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Towards Sustainable Carbon Return from Waste to Industry via C2-Type Molecular Unit.

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Towards Sustainable Carbon Return from Waste to Industry via C<sub>2</sub>-Type Molecular Unit.

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OmicsDI is part of the ELIXIR infrastructure

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Towards Sustainable Carbon Return from Waste to Industry via C₂-Type Molecular Unit.