A Ratiometric Fluorescent Sensor Based on Dye/Tb (III) Functionalized UiO-66 for Highly Sensitive Detection of TDGA.

ABSTRACT: Thiodiglycolic acid (TDGA) is a biomarker for monitoring vinyl chloride exposure. Exploring a facile, rapid and precise analysis technology to quantify TDGA is of great significance. In this research, we demonstrate a fluorescent sensor based on dual-emissive UiO-66 for TDGA detection. This ratiometric fluorescent material named C460@Tb-UiO-66-(COOH)₂ was designed and synthesized by introducing organic dye 7-diethylamino-4-methylcoumarin (C460) and Tb³⁺ into UiO-66-(COOH)₂. The as-obtained C460@Tb-UiO-66-(COOH)₂ samples showed highly selective recognition, excellent anti-interference and rapid response characteristics for the recognition of TDGA. The detection limit is 0.518 mg·mL^-1, which is much lower than the threshold of 20 mg·mL

SUBMITTER: Fan Y 

PROVIDER: S-EPMC9570906 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature