Self-Assembly of Supramolecular Architectures Driven by σ-Hole Interactions: A Halogen-Bonded 2D Network Based on a Diiminedibromido Gold(III) Complex and Tribromide Building Blocks.

ABSTRACT: The reaction of the complex [Au(phen)Br₂](PF₆) (phen = 1,10-phenanthroline) with molecular dibromine afforded {[Au(phen)Br₂](Br₃)}_∞ (1). Single crystal diffraction analysis showed that the [Au(phen)Br₂]⁺ complex cations were bridged by asymmetric tribromide anions to form infinite zig-zag chains featuring the motif ···Au-Br···Br-Br-Br···Au-Br···Br-Br-Br···. The complex cation played an unprecedented halogen bonding (XB) donor role engaging type-I and type-II XB noncovalent interactions of comparable strength with symmetry related [Br₃]^- anions. A network of hydrogen bonds connects parallel chains in an infinite 2D network, contributing to the layered supramolecular architecture. DFT ca

SUBMITTER: Aragoni MC 

PROVIDER: S-EPMC9571214 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature