High Throughput Preparation of Ag-Zn Alloy Thin Films for the Electrocatalytic Reduction of CO₂ to CO.

ABSTRACT: Ag-Zn alloys are identified as highly active and selective electrocatalysts for CO₂ reduction reaction (CO₂RR), while how the phase composition of the alloy affects the catalytic performances has not been systematically studied yet. In this study, we fabricated a series of Ag-Zn alloy catalysts by magnetron co-sputtering and further explored their activity and selectivity towards CO₂ electroreduction in an aqueous KHCO₃ electrolyte. The different Ag-Zn alloys involve one or more phases of Ag, AgZn, Ag₅Zn₈, AgZn_3, and Zn. For all the catalysts, CO is the main product, likely due to the weak CO binding energy on the catalyst surface. The Ag₅Zn₈ and AgZn₃ catalysts show a higher CO se

SUBMITTER: Sun J 

PROVIDER: S-EPMC9571298 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature