Field-Induced Slow Magnetic Relaxation in Co^II Cyclopropane-1,1-dicarboxylates.

ABSTRACT: New Co^II substituted malonate field-induced molecular magnets {[Rb₆Co₃(cpdc)₆(H₂O)₁₂]∙6H₂O}_n (1) and [Cs₂Co(cpdc)₂(H₂O)₆]_n (2) (where cpdc^2- stands for cyclopropane-1,1-dicarboxylic acid dianions) were synthesized. Both compounds contain mononuclear bischelate fragments {Co^II(cpdc)₂(H₂O)₂}^2- where the quasi-octahedral cobalt environment (CoO₆) is complemented by water molecules in apical positions. The alkali metal atoms play the role of connectors between the bischelate fragments to form 3D and 2D polymeric structures for 1 and

SUBMITTER: Matyukhina AK 

PROVIDER: S-EPMC9572064 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature