An Ultrastable Porous Polyhedral Oligomeric Silsesquioxane/Tetraphenylthiophene Hybrid as a High-Performance Electrode for Supercapacitors.

ABSTRACT: In this study, we synthesized three hybrid microporous polymers through Heck couplings of octavinylsilsesquioxane (OVS) with 2,5-bis(4-bromophenyl)-1,3,4-oxadiazole (OXD-Br₂), tetrabromothiophene (Th-Br₄), and 2,5-bis(4-bromophenyl)-3,4-diphenylthiophene (TPTh-Br₂), obtaining the porous organic-inorganic polymers (POIPs) POSS-OXD, POSS-Th, and POSS-TPTh, respectively. Fourier transform infrared spectroscopy and solid state ¹³C and ²⁹Si NMR spectroscopy confirmed their chemical structures. Thermogravimetric analysis revealed that, among these three systems, the POSS-Th POIP possessed the highest thermal stability (T₅: 586 °C; T₁₀: 785 °C; char yield: 90 wt%), presumably because of a strongly crosslinked network for

SUBMITTER: Ejaz M 

PROVIDER: S-EPMC9572779 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature