Synthesis, thermal behaviors, and energetic properties of asymmetrically substituted tetrazine-based energetic materials

ABSTRACT: 1,2,4,5-tetrazine ring is a common structure for the construction of energy-containing compounds, and its high nitrogen content and large conjugation effect give it the advantage of a good balance between energy and mechanical stability as a high-nitrogen energy-containing material. However, most of the reported works about tetrazine energetic materials (EMs) are symmetrically substituted tetrazines due to their easy accessibility. A small number of reports show that asymmetrically substituted tetrazines also have good properties, such as high density and generation of enthalpy and energy. Herein, two asymmetrically substituted tetrazines and their five energetic salts were prepared and fully characterized by IR spectroscopy, NMR spectra, elemental analysis, and differential scanning calor

SUBMITTER: Wang S 

PROVIDER: S-EPMC9574065 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature