Aggregation-induced polarization (AIP) of derivatives of BINOL and BINAP.

ABSTRACT: The relationship between optical rotations of small chiral molecules with water% in THF has been established. The typical aggregation co-solvent systems resulted in optical rotation amplification and adjustment, defined as aggregation-induced polarization (AIP). The AIP work can serve as a new tool to determine molecular aggregation, especially for those that cannot display aggregation-induced emission (AIE). Therefore, AIP and AIE are anticipated to complement each other. In addition, AIP can also serve as a new transmission tool providing adjusting right- or left-hand polarized lights of a series of individual wavelengths. Since chiral phosphine derivatives are among the most important ligands, this work would benefit research using chiral aggregates to control asymmetric synthesis and c

SUBMITTER: Tang Y 

PROVIDER: S-EPMC9578015 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature