Interplay between Transition-Metal K-edge XMCD and Magnetism in Prussian Blue Analogs.

ABSTRACT: To disentangle the information contained in transition-metal K-edge X-ray magnetic circular dichroism (XMCD), two series of Prussian blue analogs (PBAs) were investigated as model compounds. The number of 3d electrons and the magnetic orbitals have been varied on both sites of the bimetallic cyanide polymer by combining with the hexacyanoferrate or the hexacyanochromate entities' various divalent metal ions A²⁺ (Mn²⁺, Fe²⁺, Co²⁺, Ni²⁺, and Cu²⁺). These PBA were studied by Fe and Cr X-ray absorption spectroscopy and XMCD. The results, compared to those obtained at the A K-edges in a previous work, show that transition-metal K-edge XMCD is very sensitive to orbital symmetry and can therefore give valuable information on the lo

SUBMITTER: N'Diaye A 

PROVIDER: S-EPMC9583310 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature