C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles.

ABSTRACT: Five- and six-coordinate cationic bis(phosphine) cobalt(III) metallacycle complexes were synthesized with the general structures, [(depe)Co(cycloneophyl)(L)(L')][BAr^F₄] (depe = 1,2-bis(diethylphosphino)ethane; cycloneophyl = [κ-C:C-(CH₂C(Me)₂)C₆H₄]; L/L' = pyridine, pivalonitrile, or the vacant site, BAr₄^F = B[(3,5-(CF₃)₂)C₆H₃]₄). Each of these compounds promoted facile directed C(sp²)-H activation with exclusive selectivity for ortho-alkylated products, consistent with the selectivity of reported cobalt-catalyzed arene-alkene-alkyne coupling reactions. The direct observation of C-H activation by cobalt(III) metallacy

SUBMITTER: Whitehurst WG 

PROVIDER: S-EPMC9585578 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature