Colloidal Synthesis and Photocatalytic Properties of Cu₃NbS₄ and Cu₃NbSe₄ Sulvanite Nanocrystals.

ABSTRACT: Niobium sulvanites Cu₃NbX₄ (X = S, Se) have been theoretically predicted as promising candidates for solar photovoltaics and photocatalytic water splitting. This report outlines the first synthesis of Cu₃NbS₄ and Cu₃NbSe₄ in a nanocrystalline form. The crystal structures were investigated by X-ray diffraction, identity was confirmed by Raman spectroscopy, and the optoelectronic properties and morphology of Cu₃NbS₄ and Cu₃NbSe₄ nanocrystals were examined by UV-vis spectroscopy and transmission electron microscopy, respectively. To gain insight into the Cu₃NbX₄ formation, a mechanistic study was conducted for Cu₃NbSe₄ monitoring the nanopar

SUBMITTER: Chang CY 

PROVIDER: S-EPMC9585635 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature