Interfacial water engineering boosts neutral water reduction.

ABSTRACT: Hydrogen evolution reaction (HER) in neutral media is of great practical importance for sustainable hydrogen production, but generally suffers from low activities, the cause of which has been a puzzle yet to be solved. Herein, by investigating the synergy between Ru single atoms (RuNC) and RuSe_x cluster compounds (RuSe_x) for HER using ab initio molecular dynamics, operando X-ray absorption spectroscopy, and operando surface-enhanced infrared absorption spectroscopy, we establish that the interfacial water governs neutral HER. The rigid interfacial water layer in neutral media would inhibit the transport of H₂O*/OH* at the electrode/electrolyte interface of RuNC, but the RuSe_x can promote H₂O*/OH* transport to increase the number of ava

SUBMITTER: Sun K 

PROVIDER: S-EPMC9587018 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature