Ti/Ni co-doped perovskite cathode with excellent catalytic activity and CO2 chemisorption ability via nanocatalysts exsolution for solid oxide electrolysis cell.
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ABSTRACT: Carbon dioxide (CO2) gas is the main cause of global warming and has a significant effect on both climate change and human health. In this study, Ni/Ti co-doped Sr1.95Fe1.2Ni0.1Ti0.2Mo0.5O6-δ (SFNTM) double perovskite oxides were prepared and used as solid oxide electrolysis cell (SOEC) cathode materials for effective CO2 reduction. Ti-doping enhances the structural stability of the cathode material and increases the oxygen vacancy concentration. After treatment in 10% H2/Ar at 800°C, Ni nanoparticles were exsolved in situ on the SFNTM surface (Ni@SFNTM), thereby improving its chemisorption and activation capacity for CO2. Modified by the Ti-doping and the in situ exs
SUBMITTER: Zhen S
PROVIDER: S-EPMC9589057 | biostudies-literature | 2022
REPOSITORIES: biostudies-literature
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