Large Room Temperature Bulk DNP of ¹³C via P1 Centers in Diamond.

ABSTRACT: We use microwave-induced dynamic nuclear polarization (DNP) of the substitutional nitrogen defects (P1 centers) in diamond to hyperpolarize bulk ¹³C nuclei in both single crystal and powder samples at room temperature at 3.34 T. The large (>100-fold) enhancements demonstrated correspond to a greater than 10 000-fold improvement in terms of signal averaging of the 1% abundant ¹³C spins. The DNP was performed using low-power solid state sources under static (nonspinning) conditions. The DNP spectrum (DNP enhancement as a function of microwave frequency) of diamond powder shows features that broadly correlate with the EPR spectrum. A well-defined negative Overhauser peak and two solid effect peaks are observed for the central (m _I = 0) manifold o

SUBMITTER: Shimon D 

PROVIDER: S-EPMC9589901 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature