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Dehydropolymerization of H₃B·NMeH₂ Mediated by Cationic Iridium(III) Precatalysts Bearing κ³- ⁱ Pr-PN ^R P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism.

ABSTRACT: The dehydropolymerization of H₃B·NMeH₂ to form N-methylpolyaminoborane using neutral and cationic catalysts based on the {Ir( ⁱ Pr-PN^HP)} fragment [ ⁱ Pr-PN^HP = κ³-(CH₂CH₂P ⁱ Pr₂)₂NH] is reported. Neutral Ir( ⁱ Pr-PN^HP)H₃ or Ir( ⁱ Pr-PN^HP)H₂Cl precatalysts show no, or poor and unselective, activity respectively at 298 K in 1,2-F₂C₆H₄ solution. In contrast, addition of [NMeH₃][BAr^F ₄] (Ar^F = 3,5-(CF₃)₂C₆H₃) to Ir( ⁱ Pr

SUBMITTER: Brodie CN

PROVIDER: S-EPMC9594342 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature

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Dehydropolymerization of H₃B·NMeH₂ Mediated by Cationic Iridium(III) Precatalysts Bearing κ³- ⁱ Pr-PN ^R P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism.

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Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3- i Pr-PN R P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism.

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OmicsDI is part of the ELIXIR infrastructure

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Dehydropolymerization of H₃B·NMeH₂ Mediated by Cationic Iridium(III) Precatalysts Bearing κ³- ⁱ Pr-PN ^R P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism.