Catalytically Active Multicompartment Micelles.

ABSTRACT: This article presents the self-assembly behavior of multicompartment micelles (MCMs) in water into morphologies with multiple segregated domains and their use as supports for aqueous catalysis. A library of poly(norbornene)-based amphiphilic bottlebrush copolymers containing covalently attached l-proline in the hydrophobic, styrene, and pentafluorostyrene domains and a poly(ethylene glycol)-containing repeat unit as the hydrophilic block have been synthesized using ring-opening metathesis polymerization. Interaction parameter (χ) values between amphiphilic blocks were determined using a Flory-Huggins-based computational model. The morphologies of the MCMs are observed via cryogenic transmission electron microscopy and modeled using dissipative particle dynamic simulations. The catalytic ac

SUBMITTER: Ahmed E 

PROVIDER: S-EPMC9597600 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature