Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction.

ABSTRACT: Two Ni complexes are reported with κ⁴-P₂N₂ β-diimino (BDI) ligands with the general formula [Ni(XBDI)](BF₄)₂, where BDI is N-(2-(diphenylphosphaneyl)ethyl)-4-((2-(diphenylphosphaneyl)ethyl)imino)pent-2-en-2-amine and X indicates the substituent in the α-carbon intradiimine position, X = H for 1(BF₄)₂ and X = Ph for 2(BF₄)₂. Electrochemical analysis together with UV-vis and NMR spectroscopy in acetonitrile and dimethylformamide (DMF) indicates the conversion of the β-diimino complexes 1²⁺ and 2²⁺ to the negatively charged β-diketiminato (BDK) analogues (1-H)⁺ and (2-H)⁺ via deprotonation in DMF. Moreov

SUBMITTER: Jameei Moghaddam N 

PROVIDER: S-EPMC9597662 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature