Mixture of Anthraquinone Sulfo-Derivatives as an Inexpensive Organic Flow Battery Negolyte: Optimization of Battery Cell.

ABSTRACT: Anthraquinone-2,7-disulfonic acid (2,7-AQDS) is a promising organic compound, which is considered as a negolyte for redox flow batteries as well as for other applications. In this work we carried out a well-known reaction of anthraquinone sulfonation to synthesize 2,7-AQDS in mixture with other sulfo-derivatives, namely 2,6-AQDS and 2-AQS. Redox behavior of this mixture was evaluated with cyclic voltammetry and was almost identical to 2,7-AQDS. Mixture was then assessed as a potential negolyte of anthraquinone-bromine redox flow battery. After adjusting membrane-electrode assembly composition (membrane material and flow field)), the cell demonstrated peak power density of 335 mW cm^-2 (at SOC 90%) and capacity utilization, capacity retention and energy efficiency of 87.9, 99.6 an

SUBMITTER: Petrov M 

PROVIDER: S-EPMC9607404 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature