Post-Functionalization of Organometallic Complexes via Click-Reaction.

ABSTRACT: CuAAC (Cu catalyzed azide-alkyne cycloaddition) click-reaction is a simple and powerful method for the post-synthetic modification of organometallic complexes of transition metals. This approach allows the selective introduction of additional donor sites or functional groups to the periphery of the ligand environment. This is especially important if a metalloligand with free donor sites, which are of the same nature as the primary site for the coordination of the primary metal, has to be created. The concept of post-synthetic modification of organometallic complexes by click-reaction is relatively recent and the currently available experimental material does not yet allow us to identify trends and formulate recommendations to address specific problems. In the present study, we have applied

SUBMITTER: Petrovskii S 

PROVIDER: S-EPMC9614606 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature