Dataset Information

Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts.

ABSTRACT: Secondary organic aerosol (SOA) plays a critical, yet uncertain, role in air quality and climate. Once formed, SOA is transported throughout the atmosphere and is exposed to solar UV light. Information on the viscosity of SOA, and how it may change with solar UV exposure, is needed to accurately predict air quality and climate. However, the effect of solar UV radiation on the viscosity of SOA and the associated implications for air quality and climate predictions is largely unknown. Here, we report the viscosity of SOA after exposure to UV radiation, equivalent to a UV exposure of 6 to 14 d at midlatitudes in summer. Surprisingly, UV-aging led to as much as five orders of magnitude increase in viscosity compared to unirradiated SOA. This increase in viscosity can be rationalized in part by an increase in molecular mass and oxidation of organic molecules constituting the SOA material, as determined by high-resolution mass spectrometry. We demonstrate that UV-aging can lead to an increased abundance of aerosols in the atmosphere in a glassy solid state. Therefore, UV-aging could represent an unrecognized source of nuclei for ice clouds in the atmosphere, with important implications for Earth's energy budget. We also show that UV-aging increases the mixing times within SOA particles by up to five orders of magnitude throughout the troposphere with important implications for predicting the growth, evaporation, and size distribution of SOA, and hence, air pollution and climate.

SUBMITTER: Baboomian VJ

PROVIDER: S-EPMC9618061 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature

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Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts.

Baboomian Vahe J VJ Crescenzo Giuseppe V GV Huang Yuanzhou Y Mahrt Fabian F Shiraiwa Manabu M Bertram Allan K AK Nizkorodov Sergey A SA

Proceedings of the National Academy of Sciences of the United States of America 20221021 43

Secondary organic aerosol (SOA) plays a critical, yet uncertain, role in air quality and climate. Once formed, SOA is transported throughout the atmosphere and is exposed to solar UV light. Information on the viscosity of SOA, and how it may change with solar UV exposure, is needed to accurately predict air quality and climate. However, the effect of solar UV radiation on the viscosity of SOA and the associated implications for air quality and climate predictions is largely unknown. Here, we rep ...[more]

PMID: 36269861

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Project description:Condensable particulate matter (CPM) emitted from stationary combustion and mobile sources exhibits high emissions and a large proportion of organic components. However, CPM is not generally measured when conducting emission surveys of PM in most countries, including China. Consequently, previous emission inventories have not included emission rates for CPM. Here, we construct an emission inventory of CPM in China with a focus on organic aerosols (OAs) based on collected CPM emission information. Results show that OA emissions are enhanced twofold after the inclusion of CPM in a new inventory for China for the years 2014 and 2017. Considering organic CPM emissions and model representations of secondary OA (SOA) formation from CPM, a series of sensitivity cases have been simulated here using the three-dimensional Community Multiscale Air Quality (CMAQ) model to estimate the contributions of CPM emissions to atmospheric OA and fine PM (PM2.5, particulate matter with aerodynamic diameter not exceeding 2.5 μm) concentrations in China. Compared with observations at a Beijing site during a haze episode from 14 October to 14 November 2014, estimates of the temporal average primary OA (POA) and SOA concentrations were greatly improved after including the CPM effects. These scenarios demonstrated the significant contributions of CPM emissions from stationary combustion and mobile sources to the POA (51 %-85 %), SOA (42 %-58 %), and total OA concentrations (45 %-75 %). Furthermore, the contributions of CPM emissions to total OA concentrations were demonstrated over the 2 major cities and 26 other cities of the Beijing-Tianjin-Hebei region (hereafter referred to as the "BTH2 + 26 cities") in December 2018, with average contributions of up to 49 %, 53 %, 54 %, and 50 % for Handan, Shijiazhuang, Xingtai, and Dezhou, respectively. Correspondingly, the inclusion of CPM emissions also narrowed the gap between simulated and observed PM2.5 concentrations over the BTH2 + 26 cities. These results improve the simulation performance of atmospheric OA and PM2.5 and may also provide important implications for the sources of OA.

Dataset Information

Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts.

Publications

Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts.

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