Plumbojarosite formation in contaminated soil to mitigate childhood exposure to lead, arsenic and antimony.

ABSTRACT: In this study, a novel method for lead (Pb) immobilization was developed in contaminated soils using iron (III) (Fe³⁺) in conjunction with 0.05 M H₂SO₄. During method optimization, a range of microwave treatment times, solid to solution ratios, and Fe₂(SO₄)₃/H₂SO₄ concentrations were assessed using a mining/smelting impacted soil (BHK2, Pb: 3031 mg/kg), followed by treatment of additional Pb contaminated soils (PP, Pb: 1506 mg/kg, G10, Pb: 2454 mg/kg and SoFC-1, Pb: 6340 mg/kg) using the optimized method. Pb bioaccessibility was assessed using USEPA Method 1340, with Pb speciation determined by X-ray Absorption (XAS) spectroscopy. Treatment efficacy was also validated using an in vivo mouse assay, where

SUBMITTER: Kastury F 

PROVIDER: S-EPMC9619228 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature