Ontology highlight
ABSTRACT:
SUBMITTER: Gomes EO
PROVIDER: S-EPMC9619963 | biostudies-literature | 2022 Oct
REPOSITORIES: biostudies-literature
Gomes Eduardo O EO Gouveia Amanda F AF Gracia Lourdes L Lobato Álvaro Á Recio J Manuel JM Andrés Juan J
The journal of physical chemistry letters 20221017 42
The chemical pressure approach offers a new paradigm for property control in functional materials. In this work, we disclose a correlation between the β → α pressure-induced phase transition in SnMoO<sub>4</sub> and the substitution process of Mo<sup>6+</sup> by W<sup>6+</sup> in SnMo<sub>1-<i>x</i></sub>W<sub><i>x</i></sub>O<sub>4</sub> solid solutions (<i>x</i> = 0-1). Special attention is paid to discriminating the role of the lone pair Sn<sup>2+</sup> cation from the structural distortive ef ...[more]