Chain transfer agents for the catalytic ring opening metathesis polymerization of norbornenes.

ABSTRACT: Here, we present a detailed study of the metathesis activity of conjugated 1,3 diene derivatives in ring opening metathesis polymerization (ROMP) using Grubbs' 3rd generation catalyst (G3). A comprehensive screening of those derivatives revealed that monosubstituted 1,3 dienes show similar reactivities towards G3-alkylidenes as norbornene derivatives. Therefore, they represent perfect candidates for chain transfer agents in a kinetically controlled catalytic ROMP. This unprecedented reactivity allowed us to catalytically synthesize mono-end-functional poly(norborneneimide)s on the gram scale. Much more complex architectures such as star-shaped polymers could also be synthesized catalytically for the very first time via ROMP. This inexpensive and greener route to produce telechelic R

SUBMITTER: Mandal I 

PROVIDER: S-EPMC9629056 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature