Push and Pull Effect of Methoxy and Nitro Groups Modifies the Spin-State Switching Temperature in Fe(III) Complexes.

ABSTRACT: We have explored the impact of electron-donating (methoxy) and electron-withdrawing (nitro) substituents on SalEen ligand based spin crossover (SCO) behavior of Fe(III) complexes. Thus, 3-X-substituted SalEen ligands were employed to prepare [Fe(3-X-SalEen)₂]·NCSe, where X = OMe (1), H (2), and NO₂ (3) (3-X-SalEen is the condensation product of 3-substituted salicylaldehyde and N-ethylethylenediamine). The characteristic spin transition temperature (T _1/2) is shown to shift to a lower temperature when an electron-donating substituent (OMe) is used and to a higher temperature when an electron-withdrawing substituent (NO₂) is used. We used experimental and theoretical methods to determine the reasons for this beha

SUBMITTER: Dey B 

PROVIDER: S-EPMC9631739 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature