Construction of a High Nuclear Gadolinium Cluster with Enhanced Magnetocaloric Effect through Structural Transition.

ABSTRACT: Starting from a dinuclear complex {Gd₂(L)₂(NO₃)₄(H₂O)₂}·2(CH₃CN) (1) based on 2,6-dimethoxyphenol (HL), a nonanuclear cluster {Gd₉(L)₄(μ₄-OH)₂(μ₃-OH)₈(μ₂-OCH₃)₄(NO₃)₈ (H₂O)₈}(OH)·2H₂O (2) was obtained via modulating the amount of the ligand and base. Both of them have been structurally and magnetically characterized. Complex 1 decorates the Gd₂ core bridged by double μ₂-phenoxyl oxygen atoms and coordinated neutral CH₃CN molecules, while 2 features the Gd₉ core with a sandglass-like topology.

SUBMITTER: Hu P 

PROVIDER: S-EPMC9631744 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature