Solar-driven methanogenesis with ultrahigh selectivity by turning down H₂ production at biotic-abiotic interface.

ABSTRACT: Integration of methanogens with semiconductors is an effective approach to sustainable solar-driven methanogenesis. However, the H₂ production rate by semiconductors largely exceeds that of methanogen metabolism, resulting in abundant H₂ as side product. Here, we report that binary metallic active sites (namely, NiCu alloys) are incorporated into the interface between CdS semiconductors and Methanosarcina barkeri. The self-assembled Methanosarcina barkeri-NiCu@CdS exhibits nearly 100% CH₄ selectivity with a quantum yield of 12.41 ± 0.16% under light illumination, which not only exceeds the reported biotic-abiotic hybrid systems but also is superior to most photocatalytic systems. Further investigation reveal that the Ni-Cu-Cu hollow sites in NiCu alloys can

SUBMITTER: Ye J 

PROVIDER: S-EPMC9633801 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature