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2-Azido-N-(4-methyl-phen-yl)acetamide.

ABSTRACT: The asymmetric unit of the title compound, C₉H₁₀N₄O, comprises three independent mol-ecules, two pairs of which differ significantly in the rotational orientation of the azido group and one pair having very similar conformations; the N-N-C-C torsion angles are -173.9 (2), -102.7 (2) and -173.6 (2)°. In the crystal, each independent mol-ecule forms N-H⋯O hydrogen bonds with its glide-plane-related counterparts, forming zigzag chains extending along the c-axis direction.

SUBMITTER: Missioui M

PROVIDER: S-EPMC9635410 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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2-Azido-N-(4-methyl-phen-yl)acetamide.

Missioui Mohcine M Guerrab Walid W Alsubari Abdulsalam A Mague Joel T JT Ramli Youssef Y

IUCrData 20220729 Pt 7

The asymmetric unit of the title compound, C9H10N4O, comprises three independent mol-ecules, two pairs of which differ significantly in the rotational orientation of the azido group and one pair having very similar conformations; the N-N-C-C torsion angles are -173.9 (2), -102.7 (2) and -173.6 (2)°. In the crystal, each independent mol-ecule forms N-H⋯O hydrogen bonds with its glide-plane-related counterparts, forming zigzag chains extending along the c-ax ...[more]

PMID: 36341048

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