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Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)²⁺ cation and the benzene-1,3,5-tri-carboxyl-ate linker.

ABSTRACT: The asymmetric unit of catena-poly[[[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N ¹,N ⁴,N ⁸,N ¹¹)nickel(II)]-μ₂-5-carb-oxy-benzene-1,3-di-carboxyl-ato-κ² O ¹:O ³] octa-hydrate], {[Ni(C₉H₄O₆)(C₁₀H₂₄N₄)]·8H₂O} _n (I), consists of a macrocyclic Ni²⁺ cation, a carboxyl-ate dianion and eight highly disordered water mol-ecules of crystallization. The components of the compound catena-poly[[[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N ¹,N ⁴,N ⁸,N ¹¹)nick

SUBMITTER: Gavrish SP

PROVIDER: S-EPMC9638972 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature

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Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)²⁺ cation and the benzene-1,3,5-tri-carboxyl-ate linker.

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Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tri-carboxyl-ate linker.

OmicsDI is part of the ELIXIR infrastructure

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Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)²⁺ cation and the benzene-1,3,5-tri-carboxyl-ate linker.