Aqueous Two-Phase Interfacial Assembly of COF Membranes for Water Desalination.

ABSTRACT: Aqueous two-phase system features with ultralow interfacial tension and thick interfacial region, affording unique confined space for membrane assembly. Here, for the first time, an aqueous two-phase interfacial assembly method is proposed to fabricate covalent organic framework (COF) membranes. The aqueous solution containing polyethylene glycol and dextran undergoes segregated phase separation into two water-rich phases. By respectively distributing aldehyde and amine monomers into two aqueous phases, a series of COF membranes are fabricated at water-water interface. The resultant membranes exhibit high NaCl rejection of 93.0-93.6% and water permeance reaching 1.7-3.7 L m^-2 h^-1 bar^-1, superior to most water desalination membranes. Interestingly, the inter

SUBMITTER: Wang H 

PROVIDER: S-EPMC9646690 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature