Ontology highlight
ABSTRACT:
SUBMITTER: Zhang JY
PROVIDER: S-EPMC9658978 | biostudies-literature | 2022 Oct
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20221025 21
In this work, we compared the hydride-donating ability of five-membered benzoheterocyclic compounds (FMB) and six-membered benzoheterocyclic compounds (SMB), isomers of DMBI and DMIZ and of DMPZ and DMPX, using detailed thermodynamic driving forces [ΔG<sup>o</sup> (XH)], kinetic intrinsic barriers (ΔG<sup>≠</sup><sub>XH/X</sub>), and thermo-kinetic parameters [ΔG<sup>≠</sup>° (XH)]. For DMBI and DMIZ, the values of ΔG<sup>o</sup> (XH), ΔG<sup>≠</sup><sub>XH/X</sub>, and ΔG<sup>≠</sup>° (XH) are ...[more]