Stabilized Lignin Nanoparticles for Versatile Hybrid and Functional Nanomaterials.

ABSTRACT: Spherical lignin nanoparticles are emerging biobased nanomaterials, but instability and dissolution in organic solvents and aqueous alkali restrict their applicability. Here, we report the synthesis of hydroxymethylated lignin nanoparticles and their hydrothermal curing to stabilize the particles by internal cross-linking reactions. These colloidally stable particles contain a high biobased content of 97% with a tunable particle size distribution and structural stability in aqueous media (pH 3 to 12) and organic solvents such as acetone, ethanol, dimethylformamide, and tetrahydrofuran. We demonstrate that the free phenolic hydroxyl groups that are preserved in the cured particles function as efficient reducing sites for silver ions, giving rise to hybrid lignin-silver nanoparticles that ca

SUBMITTER: Morsali M 

PROVIDER: S-EPMC9667459 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature