The missing link between zeolites and polyoxometalates.

ABSTRACT: Open framework materials such as zeolites and metalorganic frameworks are garnering tremendous interest because of their intriguing architecture and attractive functionalities. Thus, new types of open framework materials are highly sought after. Here, we present the discovery of completely new inorganic framework materials, where, in contrast to conventional inorganic open frameworks, the scaffold is not based on tetrahedral EO₄ (E = main group element) but octahedral MO₆ (M = transition metal) building blocks. These structural features place them closer to polyoxometalates than zeolites. The first representatives of this class of materials are [(R)₂₄(NH₄)₁₄(PO(OH)₂)₆]·[M₁₃₄(PO₃(OH,F))₉₆

SUBMITTER: Wang G 

PROVIDER: S-EPMC9668284 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature