Triazole-Bridged Zinc Dinuclear Complexes: Mechanochemical Synthesis, Crystal Structure, and Biological Activity.

ABSTRACT: Two zinc (Zn) complexes, [Zn₂(DAT)₂Cl₄] (I) and [Zn₂(DAT)₂(NO₃)₄] (II), were prepared by grinding 3,5-diamino-1,2,4-triazole (C₂H₅N₅, DAT) with Zn precursors such as ZnCl₂ and Zn(NO₃)₂, respectively. This solid-state reaction gives the corresponding Zn complex as the sole product in over 99% yield. This mechanochemical method promotes the selective formation of Zn complexes different from those obtained using the conventional solution-based route. The crystal structures of the two complexes were analyzed by single-crystal X-ray diffraction. Complex (I) crystallizes in the monoclinic space group P2₁/c, wh

SUBMITTER: Park HS 

PROVIDER: S-EPMC9670724 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature