Volatility and Nonspecific van der Waals Interaction Properties of Per- and Polyfluoroalkyl Substances (PFAS): Evaluation Using Hexadecane/Air Partition Coefficients.

ABSTRACT: Per- and polyfluoroalkyl substances (PFAS) form weak van der Waals (vdW) interactions, which render this class of chemicals more volatile than nonfluorinated analogues. Here, the hexadecane/air partition coefficient (K_Hxd/air) values at 25 °C, as an index of vdW interaction strength and volatility, were determined for 64 neutral PFAS using the variable phase ratio headspace and gas chromatographic retention methods. Log K_Hxd/air values increased linearly with increasing number of CF₂ units, and the increase in log K_Hxd/air value per CF₂ was smaller than that per CH₂. Comparison of PFAS sharing the same perfluoroalkyl chain length but with different functional groups demonstrated that K_Hxd/air

SUBMITTER: Hammer J 

PROVIDER: S-EPMC9671037 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature