Structure of Self-Initiated Photopolymerized Films: A Comparison of Models.

ABSTRACT: Self-initiated photografting and photopolymerization (SI-PGP) uses UV illumination to graft polymers to surfaces without additional photoinitiators using the monomers as initiators, "inimers". A wider use of this method is obstructed by a lack of understanding of the resulting, presumably heterogeneous, polymer structure and of the parallel degradation under continuous UV illumination. We have used neutron reflectometry to investigate the structure of hydrated SI-PGP-prepared poly(HEMA-co-PEG₁₀MA) (poly(2-hydroxyethyl methacrylate-co-(ethylene glycol)₁₀ methacrylate)) films and compared parabolic, sigmoidal, and Gaussian models for the polymer volume fraction distributions. Results from fitting these models to the data suggest that either model can be us

SUBMITTER: Nagy B 

PROVIDER: S-EPMC9671054 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature