A Water-Free In Situ HF Treatment for Ultrabright InP Quantum Dots.

ABSTRACT: Indium phosphide quantum dots are the main alternative for toxic and restricted Cd-based quantum dots for lighting and display applications, but in the absence of protecting ZnSe and/or ZnS shells, InP quantum dots suffer from low photoluminescence quantum yields. Traditionally, HF treatments have been used to improve the quantum yield of InP to ∼50%, but these treatments are dangerous and not well understood. Here, we develop a postsynthetic treatment that forms HF in situ from benzoyl fluoride, which can be used to strongly increase the quantum yield of InP core-only quantum dots. This treatment is water-free and can be performed safely. Simultaneous addition of the z-type ligand ZnCl₂ increases the photoluminescence quantum yield up to 85%. Structural analysis via XPS as well

SUBMITTER: Ubbink RF 

PROVIDER: S-EPMC9686131 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature