Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe₂BO₃F₂ as the Template.

ABSTRACT: Exploration of nonlinear optical (NLO) crystals that are competent in generating short-wavelength ultraviolet (UV, λ ≤ 266 nm, and even deep-UV, λ ≤ 200 nm) coherent light output by direct second harmonic generation (SHG) remains a formidable challenge. Herein, four UV/deep-UV NLO crystals, M₂B₄SO₁₀ (M = K, Rb, and Cs) and Rb₃B₁₁PO₁₉F₃, were successfully synthesized by evolving the KBe₂BO₃F₂ (KBBF) structure into mixed-anionic borosulfate and fluoroborophosphate systems. They display functional [B₄SO₁₀]_∞ or [B₁₁PO₁₉F₃]_∞ KBBF-type layers that are composed of [BO₃], [BO₄], and [SO₄

SUBMITTER: Li Z 

PROVIDER: S-EPMC9686211 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature