Optical Manipulation of Incident Light for Enhanced Photon Absorption in Ultrathin Organic Photovoltaics.

ABSTRACT: We attempted to improve the photon absorption of the photoactive layer in organic photovoltaic (OPV) devices by device engineering without changing their thickness. Soft nanoimprinting lithography was used to introduce a 1D grating pattern into the photoactive layer. The increase in photocurrent caused by the propagating surface plasmon-polariton mode was quantitatively analyzed by measuring the external quantum efficiency in transverse magnetic and transverse electric modes. In addition, the introduction of an ultrathin substrate with a refractive index of 1.34 improved photon absorption by overcoming the mismatched optical impedance at the air/substrate interface. As a result, the power conversion efficiency (PCE) of an ultrathin OPV with a 400 nm grating period was 8.34%, which was 11.6

SUBMITTER: Han S 

PROVIDER: S-EPMC9696273 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature