Layer-by-Layer Heterostructure of MnO₂@Reduced Graphene Oxide Composites as High-Performance Electrodes for Supercapacitors.

ABSTRACT: In this paper, δ-MnO₂ with layered structure was prepared by a facile liquid phase method, and exfoliated MnO₂ nanosheet (e-MnO₂) was obtained by ultrasonic exfoliation, whose surface was negatively charged. Then, positive charges were grafted on the surface of MnO₂ nanosheets with a polycation electrolyte of polydiallyl dimethylammonium chloride (PDDA) in different concentrations. A series of e-MnO₂@reduced graphene oxide (rGO) composites were obtained by electrostatic self-assembly combined with hydrothermal chemical reduction. When PDDA was adjusted to 0.75 g/L, the thickness of e-MnO₂ was ~1.2 nm, and the nanosheets were uniformly adsorbed on the surface of graphene, which shows layer-by-layer morphology with a sp

SUBMITTER: Liu T 

PROVIDER: S-EPMC9697611 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature