Arginine-modified black phosphorus quantum dots with dual excited states for enhanced electrochemiluminescence in bioanalysis.

ABSTRACT: The electrochemiluminescence (ECL) is generally emitted via radiative transition of singlet or triplet excited state (S₁ or T₁). Herein, an ECL mechanism with the transitions of both S₁ and T₁ of black phosphorus quantum dots (BPQDs) is found, and an arginine (Arg) modification strategy is proposed to passivate the surface oxidation defects of BPQDs, which could modulate the excited states for enhancing the ECL efficiency of BPQDs. The Arg modification leads to greater spatial overlap of highest and lowest occupied molecular orbitals, and spectral shift of radiative transitions, and improves the stability of anion radical of BPQDs. To verify the application of the proposed mechanism, it is used to construct a sensitive method for conveniently eva

SUBMITTER: Yu S 

PROVIDER: S-EPMC9701201 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature