Antifouling graphene oxide membranes for oil-water separation via hydrophobic chain engineering.

ABSTRACT: Engineering surface chemistry to precisely control interfacial interactions is crucial for fabricating superior antifouling coatings and separation membranes. Here, we present a hydrophobic chain engineering strategy to regulate membrane surface at a molecular scale. Hydrophilic phytic acid and hydrophobic perfluorocarboxylic acids are sequentially assembled on a graphene oxide membrane to form an amphiphilic surface. The surface energy is reduced by the introduction of the perfluoroalkyl chains while the surface hydration can be tuned by changing the hydrophobic chain length, thus synergistically optimizing both fouling-resistance and fouling-release properties. It is found that the surface hydration capacity changes nonlinearly as the perfluoroalkyl chain length increases from C₄

SUBMITTER: Yang C 

PROVIDER: S-EPMC9705527 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature